In-situ Investigation of the Early Stage of TiO2 epitaxy on (001) SrTiO3

We report on a systematic study of the growth of epitaxial TiO2 films deposited by pulsed laser deposition on Ti-terminated (001) SrTiO3 single crystals. By using in-situ reflection high energy electron diffraction, low energy electron diffraction, x-ray photoemission spectroscopy and scanning probe microscopy, we show that the stabilization of the anatase (001) phase is preceded by the growth of a pseudomorphic Sr-Ti-O intermediate layer, with a thickness between 2 and 4 nm. The data demonstrate that the formation of this phase is related to the activation of long range Sr migration from the substrate to the film. The role of interface Gibbs energy minimization, as a driving force for Sr diffusion, is discussed. Our results enrich the phase diagram of the Sr-Ti-O system under epitaxial strain opening the roudeficient SrTiO phase.Comment: 8 pages, 7 figure

Role of interband scattering in neutron irradiated MgB2_2 thin films by Scanning Tunneling Spectroscopy measurements

A series of MgB$_2$ thin films systematically disordered by neutron irradiation have been studied by Scanning Tunneling Spectroscopy. The c-axis orientation of the films allowed a reliable determination of local density of state of the $\pi$ band. With increasing disorder, the conductance peak moves towards higher voltages and becomes lower and broader, indicating a monotonic increase of the $\pi$ gap and of the broadening parameter. These results are discussed in the frame of two-band superconductivity.Comment: The text will be submitted in Latex format, and the corresponding pdf file should take 6 pages. There are 5 figures (eps files submitted) and 1 tabl

A therapeutic environmental enrichment programme for managing pathological behaviour in the fossa (Cryptoprocta ferox)

This study is based on an adult male fossa (Cryptoprocta ferox) that arrived at Garda Zoological Park (Italy) exhibiting stereotyped and self-injuring behaviours and follows its subsequent rehabilitation through a long-term environmental enrichment programme. Data were collected over a period of six months. Continuous focal animal sampling was used to collect behavioural data during 90-minute sessions; 24 sessions took place over the first two months and two sessions took place six months after his arrival. Data were analysed using non-parametric tests. At the beginning of the study period, the predatory behaviour of the fossa was not species-specific since he was not able to find food items when they were hidden in the enclosure. It usually interacted with items for just a few minutes. Rub-bing different scents on enclosure furniture promoted play only for a few minutes. After two months of behavioural observations, its behaviour only improved slightly and stereotyped and self-injuring behaviours were maintained. However, we continued the intense enrichment programme for a longer period. Six months after its arrival rare undesirable behaviours or noticeable side effects were ob-served whilst species-specific behaviours were recorded. Results showed that the environmental enrichment curtailed the aberrant behaviours. In conclusion, this case study provides evidence sup-porting the hypothesis that a suitable enrichment programme could have a therapeutic effect on pathological behaviour in captive animals

High quality MgB2 thin films in-situ grown by dc magnetron sputtering

Thin films of the recently discovered magnesium diboride (MgB2) intermetalic superconducting compound have been grown using a magnetron sputtering deposition technique followed by in-situ annealing at 830 C. High quality films were obtained on both sapphire and MgO substrates. The best films showed maximum Tc = 35 K (onset), a transition width of 0.5 K, a residual resistivity ratio up to 1.6, a low temperature critical current density Jc > 1 MA/cm2 and anisotropic critical field with gamma = 2.5 close to the values obtained for single crystals. The preparation technique can be easily scaled to produce large area in-situ films.Comment: 7 pages, 4 figure

Microwave intermodulation distortion of MgB2 thin films

The two tone intermodulation arising in MgB2 thin films deposited in-situ by planar magnetron sputtering on sapphire substrates is studied. Samples are characterised using an open-ended dielectric puck resonator operating at 8.8 GHz. The experimental results show that the third order products increase with the two-tone input power with a slope ranging between 1.5 and 2.3. The behaviour can be understood introducing a mechanism of vortex penetration in grain boundaries as the most plausible source of non linearities in these films. This assumption is confirmed by the analysis of the field dependence of the surface resistance, that show a linear behaviour at all temperatures under test.Comment: 13 pages, 3 figures; to be published in Appl. Phys. Let

Does degradation from selective logging and illegal activities differently impact forest resources? A case study in Ghana

Degradation, a reduction of the ecosystem’s capacity to supply goods and services, is widespread in tropical forests and mainly caused by human disturbance. To maintain the full range of forest ecosystem services and support the development of effective conservation policies, we must understand the overall impact of degradation on different forest resources. This research investigates the response to disturbance of forest structure using several indicators: soil carbon content, arboreal richness and biodiversity, functional composition (guild and wood density), and productivity. We drew upon large field and remote sensing datasets from different forest types in Ghana, characterized by varied protection status, to investigate impacts of selective logging, and of illegal land use and resources extraction, which are the main disturbance causes in West Africa. Results indicate that functional composition and the overall number of species are less affected by degradation, while forest structure, soil carbon content and species abundance are seriously impacted, with resources distribution reflecting the protection level of the areas. Remote sensing analysis showed an increase in productivity in the last three decades, with higher resiliency to change in drier forest types, and stronger productivity correlation with solar radiation in the short dry season. The study region is affected by growing anthropogenic pressure on natural resources and by an increased climate variability: possible interactions of disturbance with climate are also discussed, together with the urgency to reduce degradation in order to preserve the full range of ecosystem functions

Early mapping of industrial tomato in Central and Southern Italy with Sentinel 2, aerial and RapidEye additional data

Timely crop information, i.e. well before harvesting time and at first stages of crop development, can benefit farmers and producer organizations. The current case study documents the procedure to deliver early data on planted tomato to users, showing the potential of Sentinel 2 to map tomato at the very beginning of the crop season, which is a challenging task. Using satellite data, integrated with ground and aerial data, an initial estimate of area planted with tomato and early tomato maps were generated in seven main production areas in Italy. Estimates of the amount of area planted with tomato provided similar results either when derived from field surveys or from remote sensing-based classification. Tomato early maps showed a producer accuracy > 80% in seven cases out of nine, and a user accuracy > 80% in five cases out of nine, with differences attributed to the varying agricultural characteristics and environmental heterogeneity of the study areas. The additional use of aerial data improved producer accuracy moderately. The ability to identify abrupt growth changes, such as those caused by natural hazards, was also analysed: Sentinel 2 detected significant changes in tomato growth between a hailstorm-affected area and a control area. The study suggests that Sentinel 2, with enhanced spectral capabilities and open data policy, represents very valuable data, allowing crop monitoring at an early development stage

Electric field effect and superconducting–insulating transition in ‘123’ cuprate superconductors

The physics of high critical temperature superconductors (HTS) remains a fascinating but undisclosed issue in condensed matter. One of the most interesting topics is the transition from the insulating phase of the parent compound, having long range antiferromagnetic order, to the superconducting phase. A method to investigate in detail the superconducting to insulating (SIT) transition in HTS is to control the doping of the CuO(2) planes in a fine way. Here, by using the electric field effect on thin Nd(1)Ba(2)Cu(3)O(7) films, we present a study of the HTS phase diagram close to the SIT with unprecedented detail. By virtue of these data, we will show that doping of holes in samples located at the boundary separating the superconducting and insulating regions produces changes in the transport characteristic consistent with an electronic phase separation scenario. Some consequences of these data are the failure of standard 2D quantum scaling theory and the possible coexistence of superconducting and weakly insulating phases in this region of the phase diagram. A continuous transition between the two competing phases as a function of doping place evident constraints on the mechanism of superconductivity

COSMO-SkyMed potential to detect and monitor Mediterranean maquis fires and regrowth: a pilot study in Capo Figari, Sardinia, Italy

Mediterranean maquis is a complex and widespread ecosystem in the region, intrinsically prone to fire. Many species have developed specific adaptation traits to cope with fire, ensuring resistance and resilience. Due to the recent changes in socio-economy and land uses, fires are more and more frequent in the urban-rural fringe and in the coastlines, both now densely populated. The detection of fires and the monitoring of vegetation regrowth is thus of primary interest for local management and for understanding the ecosystem dynamics and processes, also in the light of the recurrent droughts induced by climate change. Among the main objectives of the COSMO-SkyMed radar constellation mission there is the monitoring of environmental hazards; the very high revisiting time of this mission is optimal for post-hazard response activities. However, very few studies exploited such data for fire and vegetation monitoring. In this research, Cosmo-SkyMed is used in a Mediterranean protected area covered by maquis to detect the burnt area extension and to conduct a mid-term assessment of vegetation regrowth. The positive results obtained in this research highlight the importance of the very high-resolution continuous acquisitions and the multi-polarization information provided by COSMO-SkyMed for monitoring fire impacts on vegetation